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- W2059171251 abstract "For the purpose of verifying the validity of modern fractionation theory by experimentation, atactic polystyrene in methylcyclohexane was fractionated by employing a successive solutional fractionation (SSF) method. SSF was duplicated under different operating conditions. The fractions thus prepared and those in a previous paper (Makromol. Chem., 117, 485 (1976)) were eluted through a GPC column, whose resolution factor h was very accurately determined in advance. The experimental relations of the ratio of the weight- to number-average molecular weight Mw/Mn vs. Mw obtained for three SSF runs fit in well with those predicted by the theory with p=0.7, which was already evaluated by the phase-separation experiment on the same polymer/solvent system, where p is a parameter representing concentration dependence of the thermodynamic polymer/solvent interaction parameter χ given by χ=χ0(1+pvp) (χ0, constant and vp, polymer volume fraction)." @default.
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- W2059171251 date "1977-07-01" @default.
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- W2059171251 title "An Additional Test of Modern Theory of Molecular Weight Fractionation Based on Solubility Difference" @default.
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- W2059171251 doi "https://doi.org/10.1295/polymj.9.395" @default.
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