FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2059173976> ?p ?o ?g. }

• W2059173976 endingPage "10107" @default.
• W2059173976 startingPage "10093" @default.
• W2059173976 abstract "The kinetic inertness of the hexaaquachromium(III) (kH2O=2.4x10(-6) s(-1)) has led to challenges with respect to incorporating CrIII ions into Prussian blue-type materials; however, hexakis(acetonitrile)chromium(III) was shown to be substantially more labile (approximately 10(4) times) and enables a new synthetic route for the synthesis of these materials via nonaqueous solvents. The synthesis, spectroscopic, and physical properties of Cr[M(CN)6] (M=V, Cr, Mn, Fe) Prussian blue analogues synthesized from [CrIII(NCMe)6]3+ and the corresponding [MIII(CN)6]3- are described. All these compounds {(NEt4)0.02CrIII[VIII(CN)6]0.98(BF4)(0.08).0.10MeCN (1), CrIII[CrIII(CN)6].0.16MeCN (2), CrIII[MnIII(CN)6].0.10MeCN (3), and (NEt4)0.04CrIII0.64CrIV0.40[FeII(CN)6]0.40[FeIII(CN)6]0.60(BF4)(0.16).1.02MeCN (4)} are ferrimagnets exhibiting cluster-glass behavior. Strong antiferromagnetic coupling was observed for M=V, Cr, and Mn with Weiss constants (theta) ranging from -132 to -524 K; and in 2, where the strongest coupling is observed (theta=-524 K), the highest Tc (110 K) value was observed. Weak antiferromagnetic coupling was observed for M=Fe (theta=-12 K) leading to the lowest Tc (3 K) value in this series. Weak coupling and the low Tc value observed in 4 were additionally contributed by the presence of both [FeII(CN)6]4- and [FeIII(CN)6]3- as confirmed by 57Fe-Mössbauer spectroscopy." @default.
• W2059173976 created "2016-06-24" @default.
• W2059173976 creator A5008130628 @default.
• W2059173976 creator A5045206035 @default.
• W2059173976 creator A5055587168 @default.
• W2059173976 creator A5065368279 @default.
• W2059173976 creator A5079379110 @default.
• W2059173976 date "2007-10-24" @default.
• W2059173976 modified "2023-09-25" @default.
• W2059173976 title "[CrIII(NCMe)6]3+a Labile CrIII Source Enabling Formation of Cr[M(CN)6] (M = V, Cr, Mn, Fe) Prussian Blue-Type Magnetic Materials" @default.
• W2059173976 cites W1504541190 @default.
• W2059173976 cites W1614803293 @default.
• W2059173976 cites W162701538 @default.
• W2059173976 cites W191231158 @default.
• W2059173976 cites W1964482411 @default.
• W2059173976 cites W1964664772 @default.
• W2059173976 cites W1967885766 @default.
• W2059173976 cites W1971827515 @default.
• W2059173976 cites W1983564242 @default.
• W2059173976 cites W1990491864 @default.
• W2059173976 cites W1991209862 @default.
• W2059173976 cites W1995532159 @default.
• W2059173976 cites W1995623602 @default.
• W2059173976 cites W1996465981 @default.
• W2059173976 cites W1996851018 @default.
• W2059173976 cites W1999557759 @default.
• W2059173976 cites W2003183176 @default.
• W2059173976 cites W2004779385 @default.
• W2059173976 cites W2012707823 @default.
• W2059173976 cites W2015907422 @default.
• W2059173976 cites W2021556842 @default.
• W2059173976 cites W2022185872 @default.
• W2059173976 cites W2023219625 @default.
• W2059173976 cites W2024214423 @default.
• W2059173976 cites W2027870231 @default.
• W2059173976 cites W2030446652 @default.
• W2059173976 cites W2040198503 @default.
• W2059173976 cites W2041934805 @default.
• W2059173976 cites W2045609557 @default.
• W2059173976 cites W2046471185 @default.
• W2059173976 cites W2047602127 @default.
• W2059173976 cites W2054122841 @default.
• W2059173976 cites W2054516514 @default.
• W2059173976 cites W2057980312 @default.
• W2059173976 cites W2059938646 @default.
• W2059173976 cites W2063604299 @default.
• W2059173976 cites W2069832046 @default.
• W2059173976 cites W2070539309 @default.
• W2059173976 cites W2071407931 @default.
• W2059173976 cites W2074229393 @default.
• W2059173976 cites W2079204887 @default.
• W2059173976 cites W2080033165 @default.
• W2059173976 cites W2082002130 @default.
• W2059173976 cites W2087896221 @default.
• W2059173976 cites W2090140975 @default.
• W2059173976 cites W2094439305 @default.
• W2059173976 cites W2114365222 @default.
• W2059173976 cites W2608873142 @default.
• W2059173976 cites W2950132239 @default.
• W2059173976 cites W2952300956 @default.
• W2059173976 cites W4211140163 @default.
• W2059173976 cites W4248052365 @default.
• W2059173976 doi "https://doi.org/10.1021/ic7008489" @default.
• W2059173976 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17958356" @default.
• W2059173976 hasPublicationYear "2007" @default.
• W2059173976 type Work @default.
• W2059173976 sameAs 2059173976 @default.
• W2059173976 citedByCount "13" @default.
• W2059173976 countsByYear W20591739762013 @default.
• W2059173976 countsByYear W20591739762016 @default.
• W2059173976 countsByYear W20591739762018 @default.
• W2059173976 countsByYear W20591739762020 @default.
• W2059173976 countsByYear W20591739762021 @default.
• W2059173976 countsByYear W20591739762022 @default.
• W2059173976 crossrefType "journal-article" @default.
• W2059173976 hasAuthorship W2059173976A5008130628 @default.
• W2059173976 hasAuthorship W2059173976A5045206035 @default.
• W2059173976 hasAuthorship W2059173976A5055587168 @default.
• W2059173976 hasAuthorship W2059173976A5065368279 @default.
• W2059173976 hasAuthorship W2059173976A5079379110 @default.
• W2059173976 hasConcept C121332964 @default.
• W2059173976 hasConcept C13965031 @default.
• W2059173976 hasConcept C147789679 @default.
• W2059173976 hasConcept C155355069 @default.
• W2059173976 hasConcept C17525397 @default.
• W2059173976 hasConcept C178790620 @default.
• W2059173976 hasConcept C179104552 @default.
• W2059173976 hasConcept C185592680 @default.
• W2059173976 hasConcept C26873012 @default.
• W2059173976 hasConcept C2777463227 @default.
• W2059173976 hasConcept C2779064266 @default.
• W2059173976 hasConcept C511782168 @default.
• W2059173976 hasConcept C52859227 @default.
• W2059173976 hasConcept C70854507 @default.
• W2059173976 hasConcept C8010536 @default.
• W2059173976 hasConceptScore W2059173976C121332964 @default.
• W2059173976 hasConceptScore W2059173976C13965031 @default.
• W2059173976 hasConceptScore W2059173976C147789679 @default.

• next