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- W2059175034 abstract "Abstract Three brucite-like layered Mg 2+ /M 3+ (M=Al or Ga) double hydroxides were synthesized by the coprecipitation method. The hydroxides and the mixed oxides obtained by thermal decomposition at 773 K were characterized by X-ray diffraction, infrared spectroscopy, solid-state nuclear magnetic resonance spectroscopy and thermogravimetric analysis. These techniques allowed us to confirm that double hydroxides possess a brucite-like structure where tervalent cations are octahedrally arranged and that the calcination products contain a periclase MgO phase and an amorphous Al 2 O 3 or Ga 2 O 3 phase. The surface properties of the mixed oxides and their basicities were also determined by temperature-programmed desorption of carbon dioxide. The calcination at 773 K of synthetic LDHs gave aluminum or gallium magnesium double oxides with basic sites and high specific surface areas." @default.
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- W2059175034 date "1999-07-01" @default.
- W2059175034 modified "2023-10-16" @default.
- W2059175034 title "Comparative study of Mg/Al and Mg/Ga layered double hydroxides" @default.
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- W2059175034 doi "https://doi.org/10.1016/s1387-1811(98)00345-x" @default.
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