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- W2059182783 abstract "Triethyloxonium ions, (C 2 H 5 ) 3 O + , and their deuterated analogues were produced in a tandem mass spectrometer and a Fourier transform ion cyclotron resonance mass spectrometer by ion-molecule reactions in mixtures of ethyl iodide and diethyl ether. Three ion-molecule reactions were identified as the sources of (C 2 H 5 ) 3 O + , namely (C 2 H 5 ) 2 O +. + C 2 H 5 I → (C 2 H 5 ) 3 O + + I . (1), (C 2 H 5 ) 2 OH + + C 2 H 5 I → (C 2 H 5 ) 3 O + + HI (2) and C 2 H 5 I +. + (C 2 H 5 ) 2 O → (C 2 H 5 ) 2 O + (*C 2 H 5 ) + I . (3). Reactions (1) and (3) produced stable intermediate adducts ; (2) did not. Metastable (C 5 H 5 ) 3 O + ions formed by all these reactions lost C 2 H 4 . Ions from reactions (1) and (3) were proposed to have the classical structure, and this isomer was also generated by the dissociation of the ionized adduct, [(C 2 H 5 ) 2 O . IC 2 H 5 ]] +. . Only C 2 H 4 loss from ions produced by reaction (3) showed H-D mixing in the ethyl group originally attached to iodine atom. No firm evidence was found for the participation of a non-classical H-bridged ion." @default.
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- W2059182783 date "1996-01-01" @default.
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- W2059182783 title "Continuing the search for a non-classical ethyl cation stabilized by organic molecules; the triethyloxonium ion" @default.
- W2059182783 doi "https://doi.org/10.1002/(sici)1096-9888(199601)31:1<55::aid-jms254>3.0.co;2-3" @default.
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