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- W2059197753 startingPage "1978" @default.
- W2059197753 abstract "The partial molal volumes, barV°, of [M(phen)3]Cl2 (M=Fe(II), Co(II), Ni(II), Cu(II), and Zn(II)) and 1,10-phenanthroline were determined from density measurements at 25 °C. From the values for barV° of [M(phen)3]2+, M2+ and phen the volume changes for complex formation of [M(phen)3]2+, ΔbarV°, were caluculated. Values for barV° of [M(phen)3]Cl2 varied from 445.1 cm3 mol−1 for [Fe(phen)3]Cl2 to 458.1 cm3 mol−1 for [Zn(phen)3]Cl2 and were in the order, [Fe(phen)3]2+ [Ni(phen)3]2+<[Cu(phen)3]2+<[Zn(phen)3]2+. The ΔbarV° of [Fe(phen)3]2+ was significantly small, 4.7 cm3 mol−1. While those of other metal chelate ions were similar values, ca. 20 cm3 mol−1. The smaller ΔbarV° of [Fe(phen)3]2+ is considered to be due to the spin change from the high-spin aqua ion, [Fe(OH2)6]2+, to the low-spin complex ion, [Fe(phen)3]2+." @default.
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- W2059197753 date "1983-07-01" @default.
- W2059197753 modified "2023-09-23" @default.
- W2059197753 title "Partial Molal Volumes and Volume Changes for Complex Formation of [M(phen)<sub>3</sub>]Cl<sub>2</sub>in Aqueous Solutions" @default.
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- W2059197753 doi "https://doi.org/10.1246/bcsj.56.1978" @default.
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