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- W2059284765 abstract "Abstract The diffuse reflectance spectra (25000-4000 cm−1) of some uranium (IV) complexes involving different co-ordination numbers of the central uranium ion are reported. The spectra can be divided into three classes on the basis of the band intensities. The “weak” intensity spectra occur when the co-ordination number of uranium is six and the environment is centro-symmetrical. The “strong” intensity spectra occur when the co-ordination number is higher than six and a centre of symmetry is absent. The frequencies of the “medium” intensity spectra can be correlated more closely with those of the “strong” than the “weak” intensity spectra. This indicates the absence of a centre of symmetry, and it is suggested that “medium” intensity spectra occur when octahedral or cubic symmetry is destroyed by the presence of non-equivalent ligands. The use of the three classes of spectra in predicting the environment of uranium (IV) ions in complexes is discussed." @default.
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- W2059284765 date "1965-09-01" @default.
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- W2059284765 title "Diffuse reflectance spectra of some uranium (IV) complexes" @default.
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- W2059284765 doi "https://doi.org/10.1016/0371-1951(65)80070-4" @default.
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