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- W2059286913 abstract "The reduction process of tetra-PbO in different H2SO4 solutions has been studied by linear sweep voltammetry, potential step and scanning electron microscope (SEM) techniques. As the H2SO4 concentration decreases, more tetra-PbO is formed on a lead electrode and the PbSO4 crystals and the microvoid in the anodic film enlarge. This helps the mass transfer of the H+ and SO42− ions and the transformation of tetra-PbO into basic lead sulfates and PbSO4. The reduction mechanism of tetra-PbO changes from two- into three-dimensional progressive nucleation and growth of metallic lead with the decrease of the H2SO4 concentration. When PbSO4 begins to be reduced, tetra-PbO is transformed into PbSO4, which is then reduced." @default.
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- W2059286913 date "1997-01-01" @default.
- W2059286913 modified "2023-10-18" @default.
- W2059286913 title "Effects of H2SO4 concentrations on reduction processes of PbO layer" @default.
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- W2059286913 doi "https://doi.org/10.1016/s0013-4686(96)00275-7" @default.
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