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• W2059290410 endingPage "181" @default.
• W2059290410 startingPage "173" @default.
• W2059290410 abstract "The Arrhenius parameters for the intramolecular hydrogen abstraction from the excited triplet state have been measured for several alkyl ketones. The pre-exponential factors were similar for all the ketones investigated, and their values are compatible with an adiabatic reaction path taking place through a six-membered ring activated complex. The activation energy is determined by the type of 7 hydrogen being abstracted. The photodecomposition quantum yields from the excited singlet and triplet states were measured at several temperatures. Combining these data with measurements of the triplet quantum yield provides information on the behaviour of the 1,4-biradicals produced. It is concluded that most of the biradical reactions are controlled by rotation around CC bonds." @default.
• W2059290410 created "2016-06-24" @default.
• W2059290410 creator A5028732265 @default.
• W2059290410 creator A5028876838 @default.
• W2059290410 date "1976-01-01" @default.
• W2059290410 modified "2023-10-16" @default.
• W2059290410 title "Photochemistry of alkyl ketones bearing γ-hydrogens" @default.
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• W2059290410 doi "https://doi.org/10.1016/0047-2670(76)85062-9" @default.
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