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- W2059295064 abstract "A single-crystal, room-temperature, X-ray structure determination is recorded for the title compound, NaNd(tdga)2 (‘tdga2-’ ≡ −OCOCH2SCH2COO-). Crystals are monoclinic, space group Pc, a 9·5058(4), b 7·323(1), c 9·402(4) Å, β 97·71(2)°, Z = 2 f.u., conventional R on |F| being 0·028 for No 1054 independent ‘observed’ (I > 3σ(I)) diffractometer reflections. The compound is a novel polymeric array; the neodymium atom is eight-coordinated by ligand oxygen atoms at distances ranging from 2·43(2) to 2·54(1) Å. A redetermination of the parent thiodiglycolic acid is also recorded (orthorhombic Pnam, a 5·0444(8), b 6·690(1), c 17·73(1) Å, Z = 4, R 0·038 for No 866)." @default.
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- W2059295064 date "1999-01-01" @default.
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- W2059295064 title "Structural Systematics of Rare Earth Complexes. XXI Polymeric Sodium Bis(thiodiglycolato)neodymiate(III)" @default.
- W2059295064 doi "https://doi.org/10.1071/ch98051" @default.
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