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- W2059311634 abstract "Abstract On the basis of dissolution enthalpies of Y2O3, Gd2O3, Nd2O3, Ho2O3, CuO, BaCO3, YBa2Cu3O6.9, HoBa2Cu3O6.9, GdBa2Cu3O6.9, NdBa2Cu3O6.98 measured by solution calorimetry in 6 N HCl at 323.15 K the following values were determined. (1) enthalpies of formation of Re1 2 3 phases from binary oxides: Δ ox H 0 ( Y 123, 323.15 K )=−127.5±4.6 kJ mol −1 ; Δ ox H 0 ( Ho 123, 323.15 K )=−131.4±8.6 kJ mol −1 ; Δ ox H 0 ( Gd 123, 323.15 K )=−180.0±7.3 kJ mol −1 ; Δ ox H 0 ( Nd 123, 323.15 K )=−165.0±8.8 kJ mol −1 ; (2) enthalpies of formation of Re1 2 3 phases from mixtures of Re2O3, BaCO3, CuO; (3)enthalpies of formation of Re1 2 3 phases from mixtures of Re2O3, BaCuO2, CuO; (4) standard formation enthalpies of Re1 2 3 phases Δ f H 0 ( Y 123, 323.15 K )=−2643.5±9.6 kJ mol −1 ; Δ f H 0 ( Ho 123, 323.15 K )=−2635.3±12.2 kJ mol −1 ; Δ f H 0 ( Gd 123, 323.15 K )=−2663.4±11.0 kJ mol −1 ; Δ f H 0 ( Y 123, 323.15 K )=−2632.6±12.0 kJ mol −1 . The correlations between thermodynamic data and structural parameters of Re1 2 3 phases were established. It had been noted that the stability increase was correlated with the relative difference decrease of lattice parameters of Re2O3 and BaO layers from 4.65% for BaO–Ho2O3 to 4.37% for BaO–Y2O3, 3.86% for BaO–Nd2O3, 2.42% for BaO–Gd2O3." @default.
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- W2059311634 date "1999-12-01" @default.
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- W2059311634 title "The 1:2:3 phases in the Y(Ho, Gd, Nd)–Ba–Cu–O: calorimetric investigations, correlations between thermodynamic and structural properties" @default.
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- W2059311634 doi "https://doi.org/10.1016/s0040-6031(99)00314-7" @default.
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