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- W2059348130 abstract "A series of luminescent alkynylplatinum(II) terpyridyl complexes have been synthesized and characterized by 1H NMR, IR, FAB-mass spectrometry, and elemental analysis; one of the platinum(III) complexes has also been structurally characterized by X-ray crystallography. Their electrochemical and photophysical properties have also been investigated. A majority of the complexes were able to form stable thermoreversible metallogels in organic solvents, tested by the stable-to-inversion of a test tube method. Transmission electron microscopy (TEM) and scanning electron microscopy (SEM) of the xerogels showed typical fibrous structures on the micrometer scale. Interestingly, whereas 2-OTf, 3-OTf, and 5-PF6 formed thermotropic metallogels mainly through van der Waals' forces with different emission colors, 1-X (X = OTf, BF4, PF6, and ClO4) showed additional Pt...Pt and pi-pi interactions to stabilize the resultant metallogels and showed drastic color changes during the gel-to-sol phase transition. The metallogels of 1-X were also different colors, depending on the nature of the counter anions, which governs the degree of aggregation and the extent of Pt...Pt and pi-pi interactions involved in the gelation process. This property may be utilized to serve as an effective reporter for microenvironmental changes." @default.
- W2059348130 created "2016-06-24" @default.
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- W2059348130 date "2009-06-05" @default.
- W2059348130 modified "2023-10-01" @default.
- W2059348130 title "Luminescent Alkynylplatinum(II) Terpyridyl Metallogels Stabilized by Pt···Pt, π−π, and Hydrophobic−Hydrophobic Interactions" @default.
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- W2059348130 doi "https://doi.org/10.1021/la804326c" @default.
- W2059348130 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19499924" @default.
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