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• W2059360010 abstract "A new high-order perturbation formula for the zero-field splitting of the 4A2 ground state of d3,7 ions in a trigonal field is derived on the basis of the weak-field approximation. The formula obtained is shown to be a good approximation for the cases where the cubic field parameter Dq is less than the Racah electrostatic parameter B and is thus especially suitable for tetrahedral Co2+ complexes. By using it, the zero-field splitting of ZnO:Co2+ is calculated from a parametrised d orbit and the parameters are determined from the optical spectra. The result agrees well with the experimental finding." @default.
• W2059360010 created "2016-06-24" @default.
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• W2059360010 date "1988-03-20" @default.
• W2059360010 modified "2023-10-09" @default.
• W2059360010 title "Zero-field splitting of tetrahedral Co²⁺in the trigonal crystal field" @default.
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• W2059360010 doi "https://doi.org/10.1088/0022-3719/21/8/029" @default.
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