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- W2059368506 abstract "Abstract Whereas aromatic or aliphatic phosphanes undergo cleavage of the P–C bond in the reaction with [(η 6 ‐C 6 Me 6 ) 2 Ru 2 (μ 2 ‐H) 3 ] + to give phosphido‐bridged diruthenium cations of the type [(η 6 ‐C 6 Me 6 ) 2 Ru 2 (μ 2 ‐PR 2 )(μ 2 ‐H) 2 ] + , trimethylphosphane surprisingly yields the substitution product [(η 6 ‐C 6 Me 6 )Ru 2 (PMe 3 ) 3 (μ 2 ‐H) 3 ] + ( 1 ), as well as the racemic intermediate [(η 6 ‐C 6 Me 6 ) 2 Ru 2 (PMe 3 ) 2 (μ 2 ‐H)(H) 2 ] + ( 2 ), in the form of the tetrafluoroborate salts. In complex 2 , the hydrido ligands are fluxional in solution, as shown by variable‐temperature 1 H NMR spectroscopy. Cation 1 reacts with p ‐bromothiophenol to give the complex [(η 6 ‐C 6 Me 6 ) 2 Ru 2 (PMe 3 ) 3 {μ 2 ‐( p ‐Br‐C 6 H 4 )‐S}(μ 2 ‐H) 2 ] + ( 3 ), isolated as the tetrafluoroborate salt.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
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- W2059368506 title "A Surprising Reaction of Trimethylphosphane with the Unsaturated Diruthenium Complex [(η <sup>6</sup> ‐C <sub>6</sub> Me <sub>6</sub> ) <sub>2</sub> Ru <sub>2</sub> (μ <sub>2</sub> ‐H) <sub>3</sub> ] <sup>+</sup> : Synthesis and Molecular Structure of the Cations [(η <sup>6</sup> ‐C <sub>6</sub> Me <sub>6</sub> )Ru <sub>2</sub> (PMe <sub>3</sub> ) <sub>3</sub> (μ <sub>2</sub> ‐H) <sub>3</sub> ] <sup>+</sup> and [(η <sup>6</sup> ‐C <sub>6</sub> Me <sub>6</sub> ) <sub>2</sub> Ru <sub>2</sub> (PMe…" @default.
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