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- W2059396329 abstract "(Cl3SiCCl2)2SiCl2 (1) reagiert mit einem Überschuß meMgCl (me = CH3) unter Bildung von me3SiCCSime3(2), Sime4, H2CC(Sime3) [CH(Sime3)2] (3) (Hauptprodukte) und (me3Si)2CCH(Sime3), (Nebenprodukte). Mit sinkender meMgCl-Konzentration unterbleibt die Spaltung von (1) zu (2) bis (3). Die Umsetzung beginnt mit der Umgrignardierung einer CCl-Gruppe in (1). Cl3SiCCl2SiCl2CH2SiCl3 reagiert mit meMgCl zu ; me3SiCCl2SiCl2CHClSiCl3 zu (me3Si)2CCH(Sime3). Es wird der Bildungsmechanismus angegeben. Formation of Organosilicon Compounds. LVI. Reactions of Si- and C-Chlorinated 1,3,5-Trisilapentanes with CH3MgCl (Cl3SiCCl2)2SiCl2 (1) reacts with an excess of meMgCl (me = CH3) forming me3SiCCSime3 (2), Sime4, H2CC(Sime3)[CH(Sime3)2] (3) as main products and (me3Si)2CCH(Sime3) and as by-products. The cleavage reaction of (1) to (2) and (3) does not occur when the meMgCl-concentration is lowered. The reaction is started by the formation of a GRIGNARD reagent at a CCl-group in compound (1). Cl3SiCCl2SiCl2CH2SiCl3 forms with ; me3SiCCl2SiCl2CHClSiCl3 forms (me3Si)2CCH(Sime3). A reaction sequence is given." @default.
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- W2059396329 date "1974-03-01" @default.
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- W2059396329 title "Bildung siliciumorganischer Verbindungen. LVI. Reaktionen Si- und C-chlorierter 1,3,5-Trisilapentane mit CH3MgCl" @default.
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- W2059396329 doi "https://doi.org/10.1002/zaac.19744040203" @default.
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