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• W2059403939 startingPage "4184" @default.
• W2059403939 abstract "A novel cationic, photoresponsive azobenzene derivative with the characteristic of self-assembly, 2-{4-[(E)-(4-{[11-(dodecylthio)undecyl]oxy}phenyl)diazenyl]phenoxy}-N,N,N-trimethylethanaminium bromide (1), has been synthesized. Self-assembled monolayers (SAMs) of 1 on ultrathin, transparent platinum electrodes have been fabricated and the reversible trans ⇆ cis interconversion has been demonstrated by absorption spectroscopy in transmission mode and contact angle measurements. It is shown that such photoresponsive SAMs promote the binding of anionic porphyrins at the metal surface and trigger their release upon light excitation exploiting the different light-controlled electrostatic interactions with the two isomeric forms of 1." @default.
• W2059403939 created "2016-06-24" @default.
• W2059403939 creator A5081815643 @default.
• W2059403939 creator A5090877239 @default.
• W2059403939 date "2007-01-01" @default.
• W2059403939 modified "2023-10-13" @default.
• W2059403939 title "“Catch-and-release” of porphyrins by photoswitchable self-assembled monolayers" @default.
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• W2059403939 doi "https://doi.org/10.1039/b708851e" @default.
• W2059403939 hasPublicationYear "2007" @default.
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