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- W2059434579 abstract "The authors have studied the flow birefringence and characteristic viscosities in sulphuric acid solution of a number of samples of copolyamides containing poly-p-phenylene terephthalamide and poly-p-benzamide units. From the experimental dependence of the reduced bierfringence [n]/[n] on the length of the chain using the Tsvetkov theory of flow birefringence for kinetically rigid vermiform chains, they determine the length of the Kuhn segment A = (520±60) × 10−10 m and the optical anisotropy of the monomer unit Δa=80 × 10−31m3 of the copolymers. The value of A obtained reasonably matches the theoretical for the structural model with weak hindrance of rotation." @default.
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- W2059434579 date "1981-01-01" @default.
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- W2059434579 title "Flow birefringence and rigidity of molecules of aromatic copolyamides of para-structure" @default.
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- W2059434579 doi "https://doi.org/10.1016/0032-3950(81)90205-7" @default.
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