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- W2059443419 abstract "The reduction of flavins by α-hydroxyketone enolates leads to dihydroflavins and diketones. Isoalloxazines related to flavins (good analogs for their redox chemistry) are reduced by 9,10-dihydroanthracene and succinonitrile carbanions and by propiophenone enolate (in the latter case to give the isoalloxazine radical anion). Alkali metal alcoholates, with an appropriate isoalloxazine, produce 50% yields of isoalloxazine radical ion, presumably via a substitution and electron transfer process. The ease of carbanion (and complete lack of conjugate acid) oxidation suggests a general mode of flavin redox function." @default.
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- W2059443419 date "1970-12-01" @default.
- W2059443419 modified "2023-09-23" @default.
- W2059443419 title "The oxidation of organic anions by flavins" @default.
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- W2059443419 doi "https://doi.org/10.1016/0006-291x(70)90198-1" @default.
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