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- W205944710 abstract "Review of NOx formation studies shows that NO forms in recovery furnaces primarily by two independent mechanisms, thermal and fuel. Thermal NO formation is extremely temperature-sensitive. However, theoretical predictions indicate that recovery furnace temperatures are not high enough to form significant thermal NO. Fuel NO formation is less temperature-sensitive, and is related to fuel nitrogen content. Black liquors are shown to contain 0.05 to 0.24 weight percent fuel nitrogen. Conversion of just 20% of this would yield approximately 25-120 ppm NOx (at 8% 0[sub 2]) in the flue gas, enough to represent the majority of the total NOx. Data from operating recovery furnaces show NOx emissions ranging from near zero to over 100 ppm at 8% 0[sub 2]. An apparent increase in recovery furnace NOx emissions was observed with increasing solids. This increase is much less than predicted by thermal NO formation theory, indicating that other NO formation/destruction mechanisms, such as fuel NO formation, are important. No data are available to show the relative importance of thermal and fuel NO to total NOx during black liquor combustion." @default.
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- W205944710 date "1991-10-01" @default.
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- W205944710 title "A review of NOx formation mechanisms in recovery furnaces" @default.
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