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- W2059464555 abstract "Abstract The preparation and X-ray structure analysis of the compounds [PPh 4 ] 2 [Cl 2 (S 2 )Ta(μ-O)(μ-S 2 )Ta(S 2 )Cl 2 ] ( 1 ) and [PPh 4 ] 2 -[Cl 2 (S 2 )Nb(μ-O)(μ-S 2 )Nb(S 2 )Cl 2 ] ( 2 ) are described. The anion of 1 was obtained by heating a solution of TaCl 5 with Li 2 S and S 8 in acetonitrile, while the reaction of NbCl 5 with Li 2 S 2 in acetonitrile gave the anionic complex of 2 . The two salts are isostructural and crystallize in the monoclinic space group P 2 1 / n with Z = 4. 1 : a = 12.4263(3), b = 21.5920(4), c = 19.1118(2) A, β = 95.0760(10)°, V = 5107.75(11) A 3 , and R = 0.0286 for 5719 unique reflections with I > 2 σ ( I ). 2 : a = 12.4366(3), b = 21.5875(5), c = 19.0997(4) A, β = 95.1340(10)°, V = 5107.2(2) A 3 , and R = 0.0421 for 7400 unique reflections with I > 2 σ ( I ). The metal complexes are dinuclear with bridging oxide and disulfide ligands in addition to terminal disulfide and chloride ligands and contain seven coordinate metal centers with a metal-metal distance of 3.2450(3) ( 1 ) and 3.2483(4) A ( 2 )." @default.
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- W2059464555 date "1998-06-01" @default.
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- W2059464555 title "Complexes of niobium and tantalum with chloride, sulfide and oxide ligands: synthesis and crystal structure of the (tetrachloro)bis-(η2-disulfido) (μ-oxo)(μ-η2:η2-disulfido) bismetallates [Cl2(S2) Nb(μ-O)(μ-S2)Nb(S2)Cl2]2 and [Cl2(S2)Ta(μ-O)-(μ-S2)Ta(S2)Cl2]2− as their tetraphenylphosphonium salts" @default.
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- W2059464555 doi "https://doi.org/10.1016/s0020-1693(97)06095-7" @default.
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