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- W2059521504 abstract "Polarographic investigations were carried out on vanadium(III) chloride, vanadium(V) oxoperchlorate and chromium(III) chloride in dimethylsulfoxide and N,N-dimethylformamide; the half-wave potentials (vs. aqueous saturated calomel electrode), the nature of the limiting currents, the temperature coefficients of the half-wave potentials and the wave heights, and the reversibility or irreversibility of the electrode processes were determined in 0.1 M solutions of tetraethylammonium perchlorate at 25.0°. VCl3 shows reversible VIII–VII waves, VIV is irreversibly reduced to VII, and CrCl3 exhibits a polarographic behavior corresponding to the stepwise reduction sequence CrIII–CrII –Cr0. The electrode mechanisms, the half-wave potentials in different solvents, analytical aspects and the influence of water have been discussed." @default.
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- W2059521504 date "1967-01-01" @default.
- W2059521504 modified "2023-09-27" @default.
- W2059521504 title "The polarographic behavior of transition metal compounds in dimethylsulfoxide and N,N-dimethylformanide. III. Vanadium and chromium compounds" @default.
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