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- W2059577035 abstract "In the “brush model” of polymer modified electrodes it is assumed that the polymer film consists of short and long polymer chains forming bundles in such a way that only a small part of the metal substrate surface is covered by the polymeric material. The results of electrochemical impedance spectroscopy, cyclic voltammetry and surface stress measurements confirm that a brush-like ordering of the polymer chains on the metal surface is a realistic description of the surface film structure. Physicochemical parameters obtained from electrochemical impedance spectra for poly(o-phenylenediamine) films on platinum in contact with 1 M HClO4 or 0.5 M H2SO4 solution were analyzed on the basis of the brush model. The characteristic parameters derived from the impedance spectra of different electrodes were compared." @default.
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- W2059577035 date "2006-01-01" @default.
- W2059577035 modified "2023-10-15" @default.
- W2059577035 title "The brush model of the polymer films—analysis of the impedance spectra of Au,Pt|poly(o-phenylenediamine) electrodes" @default.
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- W2059577035 doi "https://doi.org/10.1016/j.electacta.2005.02.100" @default.
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