Matches in SemOpenAlex for { <https://semopenalex.org/work/W2059587741> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W2059587741 endingPage "184" @default.
- W2059587741 startingPage "171" @default.
- W2059587741 abstract "Vibrational energy relaxation is studied for a model system with two different ligands separated by a heavy atom, there being initially an excess energy in one metal-ligand subsystem. The model has eleven coordinates to achieve a high density of states (two coordinates for one metal-ligand subsystem and nine for the other). The behavior was studied using classical and quantum mechanical methods, and the results compared. Artificial intelligence searching was used in the quantum treatment, because of the large number of potentially contributing quantum states. For the present system the adiabatic separation of motion of the local group modes, previously characterized for a C-C-Sn ligand in a smaller system, still holds when the other ligand has this high density of states. Further, the agreement between the classical and quantum results is much improved over that obtained earlier for a four-coordinate symmetric system. In the latter case isolated intrinsic resonances were responsible for the “energy transfer” which was facilitated sometimes by tunneling. The present agreement of the classical and quantum calculations is generally quantitative at shorter times and at least qualitative for longer times for most states studied. This agreement is encouraging since the former can be less computationally intensive." @default.
- W2059587741 created "2016-06-24" @default.
- W2059587741 creator A5013434500 @default.
- W2059587741 creator A5014047863 @default.
- W2059587741 creator A5015258594 @default.
- W2059587741 creator A5065369448 @default.
- W2059587741 creator A5088327041 @default.
- W2059587741 date "1989-12-01" @default.
- W2059587741 modified "2023-10-06" @default.
- W2059587741 title "Vibrational energy redistribution across a heavy atom" @default.
- W2059587741 cites W1964258290 @default.
- W2059587741 cites W1965282044 @default.
- W2059587741 cites W1965623898 @default.
- W2059587741 cites W1969001756 @default.
- W2059587741 cites W1973101091 @default.
- W2059587741 cites W1973952825 @default.
- W2059587741 cites W1979871888 @default.
- W2059587741 cites W1982777351 @default.
- W2059587741 cites W1983732233 @default.
- W2059587741 cites W1992863078 @default.
- W2059587741 cites W2000031625 @default.
- W2059587741 cites W2000258466 @default.
- W2059587741 cites W2002602554 @default.
- W2059587741 cites W2004245893 @default.
- W2059587741 cites W2009892517 @default.
- W2059587741 cites W2009906030 @default.
- W2059587741 cites W2010394612 @default.
- W2059587741 cites W2035123408 @default.
- W2059587741 cites W2038705740 @default.
- W2059587741 cites W2039758321 @default.
- W2059587741 cites W2055225826 @default.
- W2059587741 cites W2068482341 @default.
- W2059587741 cites W2069495326 @default.
- W2059587741 cites W2075557587 @default.
- W2059587741 doi "https://doi.org/10.1016/0301-0104(89)90010-4" @default.
- W2059587741 hasPublicationYear "1989" @default.
- W2059587741 type Work @default.
- W2059587741 sameAs 2059587741 @default.
- W2059587741 citedByCount "30" @default.
- W2059587741 countsByYear W20595877412017 @default.
- W2059587741 countsByYear W20595877412018 @default.
- W2059587741 crossrefType "journal-article" @default.
- W2059587741 hasAuthorship W2059587741A5013434500 @default.
- W2059587741 hasAuthorship W2059587741A5014047863 @default.
- W2059587741 hasAuthorship W2059587741A5015258594 @default.
- W2059587741 hasAuthorship W2059587741A5065369448 @default.
- W2059587741 hasAuthorship W2059587741A5088327041 @default.
- W2059587741 hasConcept C109663097 @default.
- W2059587741 hasConcept C120398109 @default.
- W2059587741 hasConcept C121332964 @default.
- W2059587741 hasConcept C149635348 @default.
- W2059587741 hasConcept C15744967 @default.
- W2059587741 hasConcept C184779094 @default.
- W2059587741 hasConcept C185592680 @default.
- W2059587741 hasConcept C2776029896 @default.
- W2059587741 hasConcept C41008148 @default.
- W2059587741 hasConcept C58312451 @default.
- W2059587741 hasConcept C62520636 @default.
- W2059587741 hasConcept C77805123 @default.
- W2059587741 hasConcept C84114770 @default.
- W2059587741 hasConceptScore W2059587741C109663097 @default.
- W2059587741 hasConceptScore W2059587741C120398109 @default.
- W2059587741 hasConceptScore W2059587741C121332964 @default.
- W2059587741 hasConceptScore W2059587741C149635348 @default.
- W2059587741 hasConceptScore W2059587741C15744967 @default.
- W2059587741 hasConceptScore W2059587741C184779094 @default.
- W2059587741 hasConceptScore W2059587741C185592680 @default.
- W2059587741 hasConceptScore W2059587741C2776029896 @default.
- W2059587741 hasConceptScore W2059587741C41008148 @default.
- W2059587741 hasConceptScore W2059587741C58312451 @default.
- W2059587741 hasConceptScore W2059587741C62520636 @default.
- W2059587741 hasConceptScore W2059587741C77805123 @default.
- W2059587741 hasConceptScore W2059587741C84114770 @default.
- W2059587741 hasIssue "1" @default.
- W2059587741 hasLocation W20595877411 @default.
- W2059587741 hasOpenAccess W2059587741 @default.
- W2059587741 hasPrimaryLocation W20595877411 @default.
- W2059587741 hasRelatedWork W1668379956 @default.
- W2059587741 hasRelatedWork W1676900334 @default.
- W2059587741 hasRelatedWork W188510070 @default.
- W2059587741 hasRelatedWork W1966566486 @default.
- W2059587741 hasRelatedWork W1995707634 @default.
- W2059587741 hasRelatedWork W2002119221 @default.
- W2059587741 hasRelatedWork W2012959172 @default.
- W2059587741 hasRelatedWork W2064440194 @default.
- W2059587741 hasRelatedWork W3199128195 @default.
- W2059587741 hasRelatedWork W2740243652 @default.
- W2059587741 hasVolume "139" @default.
- W2059587741 isParatext "false" @default.
- W2059587741 isRetracted "false" @default.
- W2059587741 magId "2059587741" @default.
- W2059587741 workType "article" @default.