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- W2059589003 abstract "Absorption coefficients for the nitrate (NO3) radical in aqueous solution have been determined using multichannel optical absorption in the range λ = 540 – 760 nm. NO3 radicals were generated by excimer laser photolysis of (NH4)2[Ce(NO3)6] at 351 nm. For the quantum yield of NO3 formation from this process a value of ϕ(NO3) = (0.85 ± 0.09) has been determined using a Br− scavenging technique. With this value the absolute absorption coefficient of NO3 at the maximum of its absorption at 635 nm was found as ϵ = (527 ± 105) l/mol · cm (base 10). Absorption coefficient data for the range 540–760 nm are presented in 2 nm intervals. The oscillator strength of the (0-0) band transition near 665 nm has been calculated to be (1.6 ± 0.5) · 10−3 in reasonable agreement with the gas phase value." @default.
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- W2059589003 date "1991-05-01" @default.
- W2059589003 modified "2023-09-27" @default.
- W2059589003 title "The Absorption Spectrum of the Nitrate (NO3) Radical in Aqueous Solution" @default.
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- W2059589003 doi "https://doi.org/10.1002/bbpc.19910950510" @default.
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