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• W2059595162 abstract "Fundamental electrostatic concepts are coupled with considerations of a quasi-dipolar solid model to account for the dependency of effective dielectric coefficients, ε, of specifically and non-specifically adsorbed electrolytes over a wide concentration range. Attention is given in quantitative detail to the variation of ε as a function of temperature, ionic strength capacitance at the point of zero charge, and the thickness of the ion-free layer. Applications to published experimental capacitance data for non-specifically adsorbed electrolytes show good agreement in most cases with different theoretical approaches suggested by the theory of structure at charged interfaces due to Bockris, Devanathan and Müller and by an earlier treatment of the double layer by Conway, Bockris and Ammar. Des concepts électrostatiques fondamentaux sont associés à un modéle solide quasidipolaire, pour rendre compte, dans un domaine étendu de concentrations, de la dépendance des coefficients diélectriques effectifs, ε, dans le cas des électrolytes spécifiquement et non spécifiquement adsorbés. L'attention est spécialement portée sur les modalités quantitatives des variations de ε avec la température, la force ionique, la capacitance au point de charge zéro et l'épaisseur de la couche exempte d'ion. Des applications faites aux données bibliographiques sur la capacitance expérimentale d'électrolytes non spécifiquement adsorbés révèlent généralement un bon accord avec différents modes d'approche théorique que suggère le modèle de structure des interfaces chargées selon Bockris, Devanathan et Müller, de même qu'une interprétation plus récente de la couche double, selon Conway, Bockris et Ammar. Fundamentale Konzepte der Elektrostatik werden zusammen mit der Vorstellung eines quasi-dipolaren Modells zur Erklärung der Abhängigkeit der effektiven Dielektrizitätskoeffizienten ε von spezifisch und nicht-spezifisch adsorbierten Elektrolyten über einen weiten Konzentrationsbereich verwendet. Insbesondere wird die Variation von ε mit den folgenden Parametern untersucht: Temperatur, Ionenstärke-Kapazität beim Ladungsnullpunkt und Dicke der Ionenfreien Schicht. Die Anwendung auf veröffentlichte experimentelle Kapazitätsdaten für nicht- spezifisch adsorbierte Elektrolyte zeigt in den meisten Fällen gute Übereinstimmung mit verschiedenen theoretischen Näherungen, wie die Theorie der Struktur an geladenen Grenzflächen nach Bockris, Devanathan und Müller, und die frühere Behandlung der Doppelschicht von Conway, Bockris und Ammar." @default.
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• W2059595162 title "Dielectric coefficients in the interphase between electrode and ionic solution" @default.
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