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- W2059602731 abstract "The complete series of arylindium halides, (C6H5)nInX3−n (n = 1, 2; X = Cl, Br, I), have been prepared using previously unreported oxidative arylation of the indium(I) halide with various mercurials, and also several published routes. Infrared and Raman spectroscopy, 115In nuclear quadrupole resonance spectroscopy, mass spectrometry and conductivity data were gathered for the purpose of structural characterization in the solid state. The compounds of stoichiometry (C6H5)2InX (X = Cl, Br, I) have best described as adopting a polymeric lattice with multiply-associated halogen atoms linking together nearly linear (C6H5)2In groups. The compounds C6H5InX2 also adopt the polymeric lattice when X = Cl, Br, but C6H5InI2 is more consistent with the associated ionic formulation, (C6H5)2In+InI4−. The dioxanate complexes, (C6H5)nInCl3−n dioxane (n = 0–3), do not contain multiply-associated chlorine atoms and aid in the characterization of the base-free compounds. The polymeric structures of the arylindium halides are more comparable to the structures of the arylthallium halides than to the arylgallium halides." @default.
- W2059602731 created "2016-06-24" @default.
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- W2059602731 date "1975-08-01" @default.
- W2059602731 modified "2023-10-16" @default.
- W2059602731 title "Synthesis and structural characterization of the arylindium halides, (C6H5)nInX3−n (X = Cl, Br, I)" @default.
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- W2059602731 doi "https://doi.org/10.1016/s0022-328x(00)86415-3" @default.
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