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- W2059618180 startingPage "2870" @default.
- W2059618180 abstract "Two-photon detachment spectroscopy of the ${mathrm{Ir}}^{ensuremath{-}}$ $({5d}^{8}{6s}^{2}{}^{3}{F}_{4})$ and ${mathrm{Pt}}^{ensuremath{-}}$ $({5d}^{9}{6s}^{2}{}^{2}{D}_{5/2})$ ions is conducted using laser intensities $ensuremath{sim}{10}^{10}$ W/c${mathrm{m}}^{2}$. Sharp resonances in the two-photon detachment yields, attributed to magnetic dipole transitions, are observed at photon energies of $7087.3ifmmodepmelsetextpmfi{}0.4$ and $9740.9ifmmodepmelsetextpmfi{}0.5{mathrm{cm}}^{ensuremath{-}1}$ for ${mathrm{Ir}}^{ensuremath{-}}$ and ${mathrm{Pt}}^{ensuremath{-}}$, respectively. Multiconfiguration Dirac-Fock calculations predict fine structure splittings of 6671 and $9535{mathrm{cm}}^{ensuremath{-}1}$ for ${mathrm{Ir}}^{ensuremath{-}}$ $(Jphantom{rule{0ex}{0ex}}=phantom{rule{0ex}{0ex}}4ensuremath{-}3)$ and ${mathrm{Pt}}^{ensuremath{-}}$ $(Jphantom{rule{0ex}{0ex}}=phantom{rule{0ex}{0ex}}5/2ensuremath{-}3/2)$, and A coefficients of 7 and $14{mathrm{s}}^{ensuremath{-}1}$, respectively, for the upper fine structure levels of the ions." @default.
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- W2059618180 date "1996-04-15" @default.
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- W2059618180 title "Two-Photon Detachment of Negative Ions via Magnetic Dipole Transitions" @default.
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- W2059618180 doi "https://doi.org/10.1103/physrevlett.76.2870" @default.
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