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- W2059622034 abstract "Irradiation of terminal olefins or cycloalkenes with Se-phenyl (selenothioperoxy)benzoate (1) gave regioselective addition products in high yield. Vinylic silanes also gave the adducts regioselectively. The stabilization effect of the α-silyl group on the alkyl radical is discussed for photolyses in carbon tetrachloride solution. The adducts obtained from vinylsilanes were efficiently converted into vinylic selenides by action of fluoride ion. The preparation of S-allyl thiobenzoate from allylsilane is also described." @default.
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- W2059622034 date "1989-01-01" @default.
- W2059622034 modified "2023-10-12" @default.
- W2059622034 title "Photo-induced selenothio esterification of olefins: radical addition to vinylsilanes" @default.
- W2059622034 doi "https://doi.org/10.1039/p19890001927" @default.
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