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- W2059628900 abstract "Addition of the triphenylphosphonium cyclopentadienylide to tetrakis(methoxycarbonyl)palladiacyclopentadiene yields the monomeric complex (cpylid)[PdC4(CO2Me4]. NMR spectra of the cyclopentadienyl ring protons indicate unsymmetrical ring coordination. A crystallographic molecular structure determination has shown that intramolecular separations between phosphonium phenyl rings and palladiacycle methyl carboxylate groups restrict the Pd to the lower region of the ylide ring. Bond lengths within the ylide ring appear to indicate allylic coordination." @default.
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- W2059628900 date "1977-01-01" @default.
- W2059628900 modified "2023-09-25" @default.
- W2059628900 title "Synthesis and structure of the triphenylphosphonium cyclopentadienylide adduct of oligomeric tetrakis(methoxycarbonyl)palladiacyclopentadiene" @default.
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- W2059628900 doi "https://doi.org/10.1016/s0022-328x(00)90052-4" @default.
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