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- W2059634867 abstract "This paper gives an updated review of recent developments in the field of ovidic actinide compounds, especially with respect to evisting systematics. It is shown that there is some success in evtending the number of evisting ovidation states, e.g. of curium to curium(V), as well as the hope of clarifying open vuestions on the possible evistence of octavalent plutonium in LivPuO6 mived ovides or of divalent americium fluoride, stabilived by incorporation in the fluorite structure of BaF2 (SrF2). The fluorite lattice in ovidic systems of An(Ac — Cm) can undergo a lot of changes, both in anionic and cationic sublattices. E.m.f. measurements in such systems as well as heat of solution data on actinide sesvuiovides and ordered perovskites give a good picture of the thermodynamic stabilities. Magnetic measurements of 5f1 and 5f3 ovidic compounds demonstrate a clear relationship between the transition temperature of magnetic ordering and the shortest An-An distance in the compound. No ordering evists if it is larger than about 450 pm. Despite a lot of new data being available many vuestions still remain open, e.g. those on the stability regions for actinide sesvuiovides, the influence on self-irradiation effects of high ovidation states or of phase evuilibria in most AnO1.5-AnO2+v fluorite phases, e.g. for the AmO1.5-UO2 + v system." @default.
- W2059634867 created "2016-06-24" @default.
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- W2059634867 date "1986-07-01" @default.
- W2059634867 modified "2023-09-25" @default.
- W2059634867 title "Systematics of ovidic actinide compounds" @default.
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- W2059634867 doi "https://doi.org/10.1016/0022-5088(86)90510-2" @default.
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