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- W2059636415 abstract "Most alkynes are volatile liquids, which are relatively difficult to use and to transport. In contrast, alkynyl carboxylic acids offer a stable and attractive alternative for the alkynylation reactions. Here, we employed alkynyl carboxylic acids as reaction partners for the alkynylation of aryl halides. Copper-catalyzed decarboxylative coupling, including various challenging aryl bromides with phenylpropiolic acid, was performed in water without using co-solvents with good yields. Our approach provides a low-loading, low-cost, stable and environmentally friendly copper catalyst system for decarboxylative coupling." @default.
- W2059636415 created "2016-06-24" @default.
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- W2059636415 date "2012-08-01" @default.
- W2059636415 modified "2023-10-16" @default.
- W2059636415 title "Copper-catalyzed decarboxylative coupling of aryl halides with alkynyl carboxylic acids performed in water" @default.
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- W2059636415 doi "https://doi.org/10.1016/j.tet.2012.06.003" @default.
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