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• W2059651601 endingPage "2573" @default.
• W2059651601 startingPage "2563" @default.
• W2059651601 abstract "The nature and extent of the effects that hydrophilic and hydrophobic solutes have on the dynamics of water molecules continues to be an area of intense experimental and theoretical investigation. In this work, we use the ultrafast optical Kerr effect to measure the picosecond dynamics and THz Raman spectral densities of a series of aqueous solutions. The solutes studied are the hydrophilic urea and formamide and the hydrophobic trimethylamine N-oxide and tetramethylurea. Measurements are made as a function of concentration between <0.1 M and >4 M. At low concentrations (<0.5 M), the THz spectrum resembles that of bulk water, but the picosecond relaxation time, reflecting dynamics in the water H-bonded network, is increased relative to bulk water for all four solutes. The extent to which water relaxation is slowed down depends on the nature of the solute, and is more pronounced for hydrophilic than for hydrophobic solutes. At concentrations above 1 M, a range of solute−solvent and solute−solute interactions gives rise to diverse solute dependent changes in the THz spectral density and to a further slowing down of the picosecond relaxation. The hydrophobic trimethylamine N-oxide has remarkably little effect on the spectral density of water, which may indicate solute self-association and the formation of water pools in more concentrated solutions. For hydrophilic urea and formamide, the THz spectral density suggests that water structure is disrupted at concentrations where most water molecules are part of a solvation shell. At such high concentrations, modes associated with the H-bonded solute make a significant contribution to the spectral density at around 100 cm−1. The hydrophobic tetramethylurea solute makes a substantial contribution to the spectral density, complicating the interpretation, but a line shape analysis suggests that it also does not strongly perturb the water structure." @default.
• W2059651601 created "2016-06-24" @default.
• W2059651601 creator A5064417354 @default.
• W2059651601 creator A5069161984 @default.
• W2059651601 creator A5078607223 @default.
• W2059651601 date "2011-02-28" @default.
• W2059651601 modified "2023-10-17" @default.
• W2059651601 title "THz Spectra and Dynamics of Aqueous Solutions Studied by the Ultrafast Optical Kerr Effect" @default.
• W2059651601 cites W1535422202 @default.
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• W2059651601 cites W1966867774 @default.
• W2059651601 cites W1970819089 @default.
• W2059651601 cites W1971263108 @default.
• W2059651601 cites W1974761920 @default.
• W2059651601 cites W1976133446 @default.
• W2059651601 cites W1976322539 @default.
• W2059651601 cites W1976734814 @default.
• W2059651601 cites W1979488801 @default.
• W2059651601 cites W1981195523 @default.
• W2059651601 cites W1984717940 @default.
• W2059651601 cites W1987169929 @default.
• W2059651601 cites W1987815728 @default.
• W2059651601 cites W1992210899 @default.
• W2059651601 cites W1998749582 @default.
• W2059651601 cites W2000995128 @default.
• W2059651601 cites W2005296205 @default.
• W2059651601 cites W2010499880 @default.
• W2059651601 cites W2013505023 @default.
• W2059651601 cites W2014243239 @default.
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• W2059651601 cites W2025714591 @default.
• W2059651601 cites W2026076675 @default.
• W2059651601 cites W2027385130 @default.
• W2059651601 cites W2028101222 @default.
• W2059651601 cites W2029589116 @default.
• W2059651601 cites W2030832856 @default.
• W2059651601 cites W2031923506 @default.
• W2059651601 cites W2034911622 @default.
• W2059651601 cites W2035520760 @default.
• W2059651601 cites W2036909158 @default.
• W2059651601 cites W2037122475 @default.
• W2059651601 cites W2044264323 @default.
• W2059651601 cites W2045933761 @default.
• W2059651601 cites W2047988910 @default.
• W2059651601 cites W2049197145 @default.
• W2059651601 cites W2053731362 @default.
• W2059651601 cites W2056431633 @default.
• W2059651601 cites W2067685498 @default.
• W2059651601 cites W2070206101 @default.
• W2059651601 cites W2073129668 @default.
• W2059651601 cites W2073464089 @default.
• W2059651601 cites W2074468510 @default.
• W2059651601 cites W2075310115 @default.
• W2059651601 cites W2078777913 @default.
• W2059651601 cites W2078913419 @default.
• W2059651601 cites W2085989165 @default.
• W2059651601 cites W2091046950 @default.
• W2059651601 cites W2091508302 @default.
• W2059651601 cites W2092233786 @default.
• W2059651601 cites W2094138262 @default.
• W2059651601 cites W2094805501 @default.
• W2059651601 cites W2102873314 @default.
• W2059651601 cites W2111057425 @default.
• W2059651601 cites W2114815940 @default.
• W2059651601 cites W2119183562 @default.
• W2059651601 cites W2131736580 @default.
• W2059651601 cites W2156336491 @default.
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• W2059651601 cites W2328990983 @default.
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• W2059651601 doi "https://doi.org/10.1021/jp111764p" @default.
• W2059651601 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21355600" @default.
• W2059651601 hasPublicationYear "2011" @default.
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