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• W2059652725 startingPage "94" @default.
• W2059652725 abstract "The reactions of FeCl3·3H2O and 2-(2′-hydroxyphenyl)-5,6-dihydro-1,3-oxazine (N–O) as a bidentate O,N donor ligand afforded a five-coordinated iron(III) complex, [Fe(N-O)2Cl], with a distorted trigonal bipyramidal configuration. The complex [Fe(N-O)2Cl] was isolated as an air-stable crystalline solid and was fully characterized, including by single-crystal X-ray structure analysis. The complex [Fe(N-O)2Cl] shows very efficient reactivity in the oxidation of sulfides to their corresponding sulfoxides using urea hydrogen peroxide (UHP) as the oxidant at room temperature under air. To get an insight into the electronic structure of the complex, the experimental studies have been accompanied by density functional theory (DFT) computations." @default.
• W2059652725 created "2016-06-24" @default.
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• W2059652725 date "2013-09-01" @default.
• W2059652725 modified "2023-09-27" @default.
• W2059652725 title "Synthesis, X-ray studies, DFT calculations and catalytic activity of a novel iron complex containing an N,O-type bidentate oxazine ligand" @default.
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• W2059652725 doi "https://doi.org/10.1016/j.poly.2013.05.049" @default.
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