FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2059667097> ?p ?o ?g. }

• W2059667097 endingPage "4761" @default.
• W2059667097 startingPage "4750" @default.
• W2059667097 abstract "A four-coordinate organoboron compound B(ppy)Mes2 (1, ppy=2-phenylpyridyl, Mes=mesityl) was previously found to undergo reversible photochromic switching through the formation/breaking of a CC bond, accompanied by a dramatic color change from colorless to dark blue. To understand this unusual phenomenon, a series of new four-coordinate boron compounds based on the ppy-chelate ligand and its derivatives have been synthesized. In addition, new N,C-chelate ligands based on benzo[b]thiophenylpyridine and indolylpyridine have also been synthesized and their boron compounds were investigated. The crystal structures of most of the new compounds were determined by X-ray diffraction analysis. UV/Vis, NMR, and electrochemical methods were used to monitor the photoisomerization process. DFT calculations were performed for all compounds to understand the photophysical and electronic properties of this class of molecules. The results of our study showed that the bulky mesityl group is necessary for photochromic switching. Electron-donating and electron-withdrawing groups on the ppy chelate have a distinct impact on the photoisomerization rate and the photochemical stability of the molecule. Furthermore, we have found that the non-ppy-based N,C-chelate ligands such as benzo[b]thiophenepyridyl can also promote photoisomerization of the boron chromophore in the same manner as the ppy chelate, but the product is thermally unstable." @default.
• W2059667097 created "2016-06-24" @default.
• W2059667097 creator A5011478333 @default.
• W2059667097 creator A5033226274 @default.
• W2059667097 creator A5050776798 @default.
• W2059667097 creator A5057524603 @default.
• W2059667097 date "2010-04-08" @default.
• W2059667097 modified "2023-09-30" @default.
• W2059667097 title "Steric and Electronic Influence on Photochromic Switching of N,C-Chelate Four-Coordinate Organoboron Compounds" @default.
• W2059667097 cites W1600846251 @default.
• W2059667097 cites W1965493566 @default.
• W2059667097 cites W1973454716 @default.
• W2059667097 cites W1974066782 @default.
• W2059667097 cites W1976461314 @default.
• W2059667097 cites W1977494417 @default.
• W2059667097 cites W1978890358 @default.
• W2059667097 cites W1978917147 @default.
• W2059667097 cites W1993392258 @default.
• W2059667097 cites W2000217444 @default.
• W2059667097 cites W2001643057 @default.
• W2059667097 cites W2002574462 @default.
• W2059667097 cites W2004343680 @default.
• W2059667097 cites W2008192551 @default.
• W2059667097 cites W2009195167 @default.
• W2059667097 cites W2015180522 @default.
• W2059667097 cites W2019265638 @default.
• W2059667097 cites W2019512570 @default.
• W2059667097 cites W2019623979 @default.
• W2059667097 cites W2021553179 @default.
• W2059667097 cites W2022395735 @default.
• W2059667097 cites W2023101016 @default.
• W2059667097 cites W2029696971 @default.
• W2059667097 cites W2030527596 @default.
• W2059667097 cites W2030818411 @default.
• W2059667097 cites W2037617777 @default.
• W2059667097 cites W2042750983 @default.
• W2059667097 cites W204421692 @default.
• W2059667097 cites W2044973933 @default.
• W2059667097 cites W2053623376 @default.
• W2059667097 cites W2055001726 @default.
• W2059667097 cites W2063411559 @default.
• W2059667097 cites W2075921885 @default.
• W2059667097 cites W2079078632 @default.
• W2059667097 cites W2079946781 @default.
• W2059667097 cites W2082560032 @default.
• W2059667097 cites W2084538732 @default.
• W2059667097 cites W2094194023 @default.
• W2059667097 cites W2095729335 @default.
• W2059667097 cites W2103221532 @default.
• W2059667097 cites W2120813594 @default.
• W2059667097 cites W2138706968 @default.
• W2059667097 cites W2148874839 @default.
• W2059667097 cites W2166648577 @default.
• W2059667097 cites W2316525498 @default.
• W2059667097 cites W2497812861 @default.
• W2059667097 cites W2952376320 @default.
• W2059667097 cites W2952483593 @default.
• W2059667097 cites W4229801553 @default.
• W2059667097 cites W4231395857 @default.
• W2059667097 doi "https://doi.org/10.1002/chem.200903582" @default.
• W2059667097 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20379976" @default.
• W2059667097 hasPublicationYear "2010" @default.
• W2059667097 type Work @default.
• W2059667097 sameAs 2059667097 @default.
• W2059667097 citedByCount "109" @default.
• W2059667097 countsByYear W20596670972012 @default.
• W2059667097 countsByYear W20596670972013 @default.
• W2059667097 countsByYear W20596670972014 @default.
• W2059667097 countsByYear W20596670972015 @default.
• W2059667097 countsByYear W20596670972016 @default.
• W2059667097 countsByYear W20596670972017 @default.
• W2059667097 countsByYear W20596670972018 @default.
• W2059667097 countsByYear W20596670972019 @default.
• W2059667097 countsByYear W20596670972020 @default.
• W2059667097 countsByYear W20596670972021 @default.
• W2059667097 countsByYear W20596670972022 @default.
• W2059667097 countsByYear W20596670972023 @default.
• W2059667097 crossrefType "journal-article" @default.
• W2059667097 hasAuthorship W2059667097A5011478333 @default.
• W2059667097 hasAuthorship W2059667097A5033226274 @default.
• W2059667097 hasAuthorship W2059667097A5050776798 @default.
• W2059667097 hasAuthorship W2059667097A5057524603 @default.
• W2059667097 hasConcept C116569031 @default.
• W2059667097 hasConcept C126661725 @default.
• W2059667097 hasConcept C161790260 @default.
• W2059667097 hasConcept C170493617 @default.
• W2059667097 hasConcept C178790620 @default.
• W2059667097 hasConcept C185592680 @default.
• W2059667097 hasConcept C192468462 @default.
• W2059667097 hasConcept C197404232 @default.
• W2059667097 hasConcept C201194858 @default.
• W2059667097 hasConcept C32123652 @default.
• W2059667097 hasConcept C32909587 @default.
• W2059667097 hasConcept C41339378 @default.
• W2059667097 hasConcept C55493867 @default.
• W2059667097 hasConcept C71240020 @default.
• W2059667097 hasConcept C75473681 @default.
• W2059667097 hasConcept C81180622 @default.

• next