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- W2059680411 abstract "Abstract 1) 1-Benzothiepineiron tricarbonyl was synthesized as a first example of thiepine-metal complex. On oxidation and decomplexation the complex gave 1-benzothiepine 1-oxide as thermally labile compound. 2) Thermolysis of a stable monocyclic thiepine gave the sulfur extruded benzene derivative together with the sulfurated product, the structure of which was confirmed by X-ray analysis. 3) The ring expansion reaction of 2,6-di-tert-butyl-4-azido-4-R-thiopyrans resulted in the formation of 1,3-thiazepine derivatives instead of the expected 1,4-thiazepines." @default.
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- W2059680411 date "1989-06-01" @default.
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- W2059680411 title "Some New Aspects of Thiepine and Thiazepine Chemistry" @default.
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- W2059680411 doi "https://doi.org/10.1080/10426508908040289" @default.
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