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- W2059707882 abstract "Several diepoxyhexanoates and epoxyhexenoates were prepared by epoxidation of methyl 2-methyl-2,4-hexadienoate or by Darzens condensation. Their 1 H- and 13C-NMR. spectra were measured and assigned. Comparison of these data with the spectra of the antibiotics hedamycin (1) and pluramycin A (2) allowed the determi-nation of the relative configurations in the side chains of these antibiotics. They were found to be (14R*,16S*,17R*,18S*) for hedamycin (1) and (14R*,16S*,17Z) for pluramycin A (2)." @default.
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- W2059707882 date "1982-02-03" @default.
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- W2059707882 title "Determination of the Relative Configurations in the Side Chains of the Antibiotics Hedamycin and Pluramycin A; Synthesis and NMR. Data of Suitable Model Compounds" @default.
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- W2059707882 doi "https://doi.org/10.1002/hlca.19820650133" @default.
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