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- W2059730180 abstract "An antiparallel orientational transition is reported for an intermetallic compound, i.e., ${mathrm{Cd}}_{6}mathrm{Ca}$ crystal, which is a $1∕1ensuremath{-}1∕1ensuremath{-}1∕1$ crystalline approximant to the icosahedral quasicrystal ${mathrm{Cd}}_{5.7}mathrm{Ca}$. A group theoretical analysis based on the Landau theory predicts that the space group of the low-temperature phase is either $C2∕c$ or $C2∕m$, in good agreement with the observations. Accordingly, two types of orientational orderings of ${mathrm{Cd}}_{4}$ tetrahedra, which are located in the center of icosahedral clusters, may occur below $100phantom{rule{0.3em}{0ex}}mathrm{K}$: In both cases, the ${mathrm{Cd}}_{4}$ tetrahedra are orientationally ordered in an antiparallel fashion along the [110] direction of the high temperature body-centered-cubic phase. Such a transition in a metal is reminiscent of orientational transitions in molecular solids." @default.
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- W2059730180 date "2005-11-29" @default.
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- W2059730180 title "Group theoretical treatment of the low-temperature phase transition of the<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mi mathvariant=normal>Cd</mml:mi><mml:mn>6</mml:mn></mml:msub><mml:mi mathvariant=normal>Ca</mml:mi></mml:mrow></mml:math><mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mn>1</mml:mn><mml:mo>∕</mml:mo><mml:mn>1</mml:mn></mml:mrow></mml:math>-cubic approximant" @default.
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- W2059730180 doi "https://doi.org/10.1103/physrevb.72.174211" @default.
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