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- W2059734568 abstract "In carbonium ions the relative orientation of the vacant p-orbital of the electron-deficient carbon atom and the C-H and C-R bonds at the adjacent carbon atom (“orbital orientation”) is a very important factor for the rates of 1,2-hydride and alkyl shifts and of cleavage of β C-C bonds. A large number of examples of this effect can be found among the reactions of directly observable carbonium ions. In some cases it causes the rate of a 1,2-shift or a β-cleavage in a cyclic carbonium ion to be several orders of magnitude lower than in acyclic carbonium ions." @default.
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- W2059734568 date "2010-09-02" @default.
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- W2059734568 title "The importance of orbital orientation as a rate-controlling factor in intramolecular reactions of carbonium ions" @default.
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