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• W2059754307 abstract "The β-ketoimine (CH3)3CC(NH2)CHC(O)C(CH3)3 (1) was synthesized by amination with dry ammonia in the presence of TiCl4. M.p. = 131 °C. IR and 1H and 13C NMR spectroscopic characterization indicates that the structure of a solution of 1 is the ketone form, and a single-crystal X-ray diffraction study shows that the structure of 1 is the enaminoketone form. The reaction of 1 with copper(II) and nickel(II) salts in solution gave chelate metal complexes: Cu[(CH3)3CC(NH)CHC(O)C(CH3)3]2 (2), M.p. = 209 °C, and Ni[(CH3)3CC(NH)CHC(O)C(CH3)3]2 (3), M.p. = 267 °C. These complexes are volatile and sublime at 180–190 °C at 5 × 10−3 Torr. An X-ray diffraction study reveals that these metal complexes are monomeric and isostructural in the solid state. In compound 2, the Cu atom has a square coordination environment: Cu–O ≈ Cu–N = 1.91 Å, ∠O–Cu–N = 91.81 Å." @default.
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• W2059754307 date "2007-09-01" @default.
• W2059754307 modified "2023-09-26" @default.
• W2059754307 title "Synthesis and properties of a new ketoiminate derivative of the 2,2,6,6-tetramethylheptane-3,5-dionate ligand to prepare volatile CVD precursors" @default.
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• W2059754307 doi "https://doi.org/10.1016/j.poly.2007.05.046" @default.
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