Matches in SemOpenAlex for { <https://semopenalex.org/work/W2059755059> ?p ?o ?g. }
Showing items 1 to 90 of
90
with 100 items per page.
- W2059755059 endingPage "128" @default.
- W2059755059 startingPage "121" @default.
- W2059755059 abstract "We report measurements of the pressure (0–30 kbar) and temperature (290–425°C) dependence of crystal (orpiment) growth rate in amorphous As2S3. All specimens were encapsulated in Pt and subjected to a 15 min “nucleation anneal” at 375 °C with 30 kbar pressure imposed; this anneal produced a 10 μm thick crystalline layer on the capsule-As2S3 interface. Growth under the other imposed conditions proceeded from this layer and its extent and morphology were determined by optical examination of the specimens after they had been quenched to 1 atm pressure and room temperature. Crystals grew in the form of sheets roughly perpendicular to the Pt-As2S3 interface. Growth in directions normal to the sheets was slow and detectable only when a pressure of ∼10 kbar was exceeded. The rate, u, of edgewise growth of the sheets was described by an equation of the form u(T, P)=u0exp-δU + PδV∗RT1-exp-(P-Pm(T)) δVmRT where Pm(T) = equilibrium melting pressure, ΔVm = volume change on melting, u0 = 6.2 × 1013 cm/s, ΔU∗ = 54.3 kcal/mol, of order of estimated AsS bond energy, and ΔV∗ = 5 cm3/mol, about 0.07 × molar volume of orpiment. u at 290° was easily measurable (∼0.13 nm/s) at 1 atm pressure. The exceptionally high glass-forming tendency of As2S3 is accounted for in terms of our kinetic results." @default.
- W2059755059 created "2016-06-24" @default.
- W2059755059 creator A5019878908 @default.
- W2059755059 creator A5035509266 @default.
- W2059755059 creator A5063775191 @default.
- W2059755059 date "1989-05-01" @default.
- W2059755059 modified "2023-09-26" @default.
- W2059755059 title "High-pressure crystallization kinetics of As2S3" @default.
- W2059755059 cites W1635348246 @default.
- W2059755059 cites W1985184263 @default.
- W2059755059 cites W1985595903 @default.
- W2059755059 cites W1995429091 @default.
- W2059755059 cites W1996009460 @default.
- W2059755059 cites W1998141434 @default.
- W2059755059 cites W2017615578 @default.
- W2059755059 cites W2052630626 @default.
- W2059755059 cites W2055354272 @default.
- W2059755059 cites W2058550908 @default.
- W2059755059 cites W2069785652 @default.
- W2059755059 cites W2086414351 @default.
- W2059755059 cites W2108570928 @default.
- W2059755059 cites W2131393222 @default.
- W2059755059 doi "https://doi.org/10.1016/0022-3093(89)90450-x" @default.
- W2059755059 hasPublicationYear "1989" @default.
- W2059755059 type Work @default.
- W2059755059 sameAs 2059755059 @default.
- W2059755059 citedByCount "19" @default.
- W2059755059 countsByYear W20597550592014 @default.
- W2059755059 countsByYear W20597550592018 @default.
- W2059755059 countsByYear W20597550592019 @default.
- W2059755059 countsByYear W20597550592020 @default.
- W2059755059 countsByYear W20597550592021 @default.
- W2059755059 countsByYear W20597550592022 @default.
- W2059755059 crossrefType "journal-article" @default.
- W2059755059 hasAuthorship W2059755059A5019878908 @default.
- W2059755059 hasAuthorship W2059755059A5035509266 @default.
- W2059755059 hasAuthorship W2059755059A5063775191 @default.
- W2059755059 hasConcept C113196181 @default.
- W2059755059 hasConcept C121332964 @default.
- W2059755059 hasConcept C13530604 @default.
- W2059755059 hasConcept C159985019 @default.
- W2059755059 hasConcept C178790620 @default.
- W2059755059 hasConcept C185592680 @default.
- W2059755059 hasConcept C192562407 @default.
- W2059755059 hasConcept C199289684 @default.
- W2059755059 hasConcept C203036418 @default.
- W2059755059 hasConcept C20556612 @default.
- W2059755059 hasConcept C26456737 @default.
- W2059755059 hasConcept C43617362 @default.
- W2059755059 hasConcept C56052488 @default.
- W2059755059 hasConcept C61048295 @default.
- W2059755059 hasConcept C8010536 @default.
- W2059755059 hasConcept C97355855 @default.
- W2059755059 hasConceptScore W2059755059C113196181 @default.
- W2059755059 hasConceptScore W2059755059C121332964 @default.
- W2059755059 hasConceptScore W2059755059C13530604 @default.
- W2059755059 hasConceptScore W2059755059C159985019 @default.
- W2059755059 hasConceptScore W2059755059C178790620 @default.
- W2059755059 hasConceptScore W2059755059C185592680 @default.
- W2059755059 hasConceptScore W2059755059C192562407 @default.
- W2059755059 hasConceptScore W2059755059C199289684 @default.
- W2059755059 hasConceptScore W2059755059C203036418 @default.
- W2059755059 hasConceptScore W2059755059C20556612 @default.
- W2059755059 hasConceptScore W2059755059C26456737 @default.
- W2059755059 hasConceptScore W2059755059C43617362 @default.
- W2059755059 hasConceptScore W2059755059C56052488 @default.
- W2059755059 hasConceptScore W2059755059C61048295 @default.
- W2059755059 hasConceptScore W2059755059C8010536 @default.
- W2059755059 hasConceptScore W2059755059C97355855 @default.
- W2059755059 hasIssue "1" @default.
- W2059755059 hasLocation W20597550591 @default.
- W2059755059 hasOpenAccess W2059755059 @default.
- W2059755059 hasPrimaryLocation W20597550591 @default.
- W2059755059 hasRelatedWork W1718772896 @default.
- W2059755059 hasRelatedWork W1965524358 @default.
- W2059755059 hasRelatedWork W2020718346 @default.
- W2059755059 hasRelatedWork W2081027925 @default.
- W2059755059 hasRelatedWork W2083131731 @default.
- W2059755059 hasRelatedWork W2112838233 @default.
- W2059755059 hasRelatedWork W2127180988 @default.
- W2059755059 hasRelatedWork W2275016807 @default.
- W2059755059 hasRelatedWork W2369210771 @default.
- W2059755059 hasRelatedWork W4366817844 @default.
- W2059755059 hasVolume "109" @default.
- W2059755059 isParatext "false" @default.
- W2059755059 isRetracted "false" @default.
- W2059755059 magId "2059755059" @default.
- W2059755059 workType "article" @default.