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• W2059767584 startingPage "1498" @default.
• W2059767584 abstract "The interaction of UHMWPE with an electron beam in vacuum and in the presence of oxygen has been investigated. UHMWPE irradiated to various doses was examined with Electron Paramagnetic Resonance (EPR) and Fourier Transform infra-red (FTIR) spectroscopies. EPR was used to explore the nature of radicals produced in UHMWPE upon irradiation and to follow their decay as a function of time. Hydroperoxides formation and distribution throughout the samples were studied with FTIR spectroscopy. A correlation between the rate of decay of macroradicals and that of hydroperoxide formation has been proposed. Accordingly, the lifetime of secondary alkyl macroradicals in the amorphous phase of the polymer was found to range approximately from 3 to 10 h." @default.
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• W2059767584 date "2007-08-01" @default.
• W2059767584 modified "2023-10-10" @default.
• W2059767584 title "Lifetime of alkyl macroradicals in irradiated ultra-high molecular weight polyethylene" @default.
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• W2059767584 doi "https://doi.org/10.1016/j.polymdegradstab.2007.05.005" @default.
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