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- W2059767738 abstract "N=Chloro-2,2,6,6-tetramethylpiperidine chlorinates primary hydrogen more rapidly than secondary hydrogen in 2,2-dimethylbutane and secondary hydrogen more rapidly than tertiary hydrogen in simple alkanes. With pentane, it chlorinates the less hindered 2-position five times faster than the more hindered 3-position. These selectivities approach the selectivity for ω (terminal) and ω-1 (penultimate) carbons that are widely exhibited by enzymic systems." @default.
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- W2059767738 date "1974-03-01" @default.
- W2059767738 modified "2023-09-24" @default.
- W2059767738 title "Sterically hindered chlorinating agents that relate to terminal biological oxidations" @default.
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- W2059767738 doi "https://doi.org/10.1016/0045-2068(74)90030-3" @default.
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