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- W2059768044 abstract "(E,E) and (Z,E) γ-alkoxy dienyl sulfones undergo nucleophilic epoxidation with remarkable regio- and stereoselectivity to render syn oxiranes in a process mainly controlled by the alkoxy stereocenter. Upon epoxidation γ-hydroxy dienyl sulfoxides provide sulfinyl and sulfonyl oxiranes along with bis-epoxides formed through a Payne rearrangement that can be prevented by silylation of the OH group. Interestingly, the presence of a γ-silyloxy group can invert the stereochemical trend of the molecule affording mainly an anti epoxidation process." @default.
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- W2059768044 date "2006-03-01" @default.
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- W2059768044 title "Nucleophilic epoxidation of γ-alkoxy dienyl sulfoxide derivatives" @default.
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- W2059768044 doi "https://doi.org/10.1016/j.tet.2005.12.024" @default.
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