FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2059791166> ?p ?o ?g. }

• W2059791166 endingPage "958" @default.
• W2059791166 startingPage "953" @default.
• W2059791166 abstract "To study metal-to-metal interactions in mixed-valence states of two weakly coupling ferrocenyl groups assembled in E or Z conformation on an ethylenic double bond, E-1,2-dimethyldiferrocenylethylene (1), Z-1,2-dimethyldi-ferrocenylethylene (2), and 1,2-diferrocenylcyclohexene (3) were synthesized and structurally characterized. Crystals of 1 are triclinic, P1, with a = 7.494(9) A, b = 10.801(3) A, c = 11.971(2) A, alpha = 102.17(2) degrees, beta = 106.12(9) degrees, gamma = 90.42(2) degrees, V = 907.8 A3, and Z = 2. Crystals of 2 are monoclinic, P2(1)/c, with a = 13.601(8) A, b = 11.104(4) A, c = 13.732(1) A, beta = 114.26(7) degrees, V = 1890.8(3) A3, and Z = 4. Crystals of 3 are orthorhombic, P2(1)2(1)2(1), with a = 5.766(2) A, b = 13.090(1) A, c = 26.695(2) A, V = 2014.9(3) A3, and Z = 4. Intervalence transition spectra (IT) and electrochemical data have been determined and compared with those of diferrocenyl-benzene (para, ortho, and meta). The comproportionation constants in nitrobenzene at 25 degrees C were found to be 490 and 813 for 1 and 3, respectively. That of 2 was not measured because of the fact that 2+ isomerizes rapidly in all solvents tested, yielding nearly a racemic mixture of E and Z conformers. This finding helps to clear the paradoxical phenomenon between experimental results of mixed-valence complexes of E- and Z-1,2-bis(1'-ethyl-1-ferrocenyl)-1,2-dimethylethylene and theories. The stability of the mixed-valence species was discussed in terms of resonance delocalization, Coulomb repulsion energy, inductive effect, magnetic interaction, structural factors, and statistical factor. According to our analysis based on the Hush formalism, the contribution due to Coulomb repulsion energy dominates the overall stability of the mixed-valence state in 1+, 2+, and 3+. Stabilization that arises from resonance delocalization is only minor and contributes less than 4% to the overall stability, even in 3+ where linked Cp rings and the ethylenic plane are coplanar. In calculating the resonance contribution, crystallographic Fe-Fe distances of 7.44 A (1) and 6.68 A (3) were used for 1+, and 3+, respectively." @default.
• W2059791166 created "2016-06-24" @default.
• W2059791166 creator A5011649648 @default.
• W2059791166 creator A5016908403 @default.
• W2059791166 creator A5030122689 @default.
• W2059791166 creator A5038670999 @default.
• W2059791166 creator A5060437490 @default.
• W2059791166 creator A5065829432 @default.
• W2059791166 date "2000-02-09" @default.
• W2059791166 modified "2023-10-09" @default.
• W2059791166 title "Metal−Metal Interactions in Weakly Coupled Mixed-Valence <i>E</i>- and <i>Z</i>-Diferrocenylethylene Complexes" @default.
• W2059791166 cites W1966377407 @default.
• W2059791166 cites W1967191398 @default.
• W2059791166 cites W1968355139 @default.
• W2059791166 cites W1969713159 @default.
• W2059791166 cites W1980038170 @default.
• W2059791166 cites W1983039005 @default.
• W2059791166 cites W1985798603 @default.
• W2059791166 cites W1999790690 @default.
• W2059791166 cites W2009400031 @default.
• W2059791166 cites W2011190695 @default.
• W2059791166 cites W2014016371 @default.
• W2059791166 cites W2032716479 @default.
• W2059791166 cites W2045515011 @default.
• W2059791166 cites W2063310592 @default.
• W2059791166 cites W2066943498 @default.
• W2059791166 cites W2073235733 @default.
• W2059791166 cites W2085044379 @default.
• W2059791166 cites W2089605181 @default.
• W2059791166 cites W2091225564 @default.
• W2059791166 cites W2317341346 @default.
• W2059791166 cites W2325829024 @default.
• W2059791166 cites W2327436785 @default.
• W2059791166 cites W2343799339 @default.
• W2059791166 cites W2346101821 @default.
• W2059791166 cites W2951537403 @default.
• W2059791166 doi "https://doi.org/10.1021/ic991084j" @default.
• W2059791166 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12526374" @default.
• W2059791166 hasPublicationYear "2000" @default.
• W2059791166 type Work @default.
• W2059791166 sameAs 2059791166 @default.
• W2059791166 citedByCount "52" @default.
• W2059791166 countsByYear W20597911662012 @default.
• W2059791166 countsByYear W20597911662013 @default.
• W2059791166 countsByYear W20597911662014 @default.
• W2059791166 countsByYear W20597911662015 @default.
• W2059791166 countsByYear W20597911662016 @default.
• W2059791166 countsByYear W20597911662017 @default.
• W2059791166 countsByYear W20597911662018 @default.
• W2059791166 countsByYear W20597911662019 @default.
• W2059791166 crossrefType "journal-article" @default.
• W2059791166 hasAuthorship W2059791166A5011649648 @default.
• W2059791166 hasAuthorship W2059791166A5016908403 @default.
• W2059791166 hasAuthorship W2059791166A5030122689 @default.
• W2059791166 hasAuthorship W2059791166A5038670999 @default.
• W2059791166 hasAuthorship W2059791166A5060437490 @default.
• W2059791166 hasAuthorship W2059791166A5065829432 @default.
• W2059791166 hasConcept C106773901 @default.
• W2059791166 hasConcept C115624301 @default.
• W2059791166 hasConcept C147789679 @default.
• W2059791166 hasConcept C161790260 @default.
• W2059791166 hasConcept C164397293 @default.
• W2059791166 hasConcept C168900304 @default.
• W2059791166 hasConcept C17525397 @default.
• W2059791166 hasConcept C178790620 @default.
• W2059791166 hasConcept C185592680 @default.
• W2059791166 hasConcept C18705241 @default.
• W2059791166 hasConcept C32909587 @default.
• W2059791166 hasConcept C37243968 @default.
• W2059791166 hasConcept C42228675 @default.
• W2059791166 hasConcept C52859227 @default.
• W2059791166 hasConcept C544153396 @default.
• W2059791166 hasConcept C55493867 @default.
• W2059791166 hasConcept C61276311 @default.
• W2059791166 hasConcept C71240020 @default.
• W2059791166 hasConcept C8010536 @default.
• W2059791166 hasConceptScore W2059791166C106773901 @default.
• W2059791166 hasConceptScore W2059791166C115624301 @default.
• W2059791166 hasConceptScore W2059791166C147789679 @default.
• W2059791166 hasConceptScore W2059791166C161790260 @default.
• W2059791166 hasConceptScore W2059791166C164397293 @default.
• W2059791166 hasConceptScore W2059791166C168900304 @default.
• W2059791166 hasConceptScore W2059791166C17525397 @default.
• W2059791166 hasConceptScore W2059791166C178790620 @default.
• W2059791166 hasConceptScore W2059791166C185592680 @default.
• W2059791166 hasConceptScore W2059791166C18705241 @default.
• W2059791166 hasConceptScore W2059791166C32909587 @default.
• W2059791166 hasConceptScore W2059791166C37243968 @default.
• W2059791166 hasConceptScore W2059791166C42228675 @default.
• W2059791166 hasConceptScore W2059791166C52859227 @default.
• W2059791166 hasConceptScore W2059791166C544153396 @default.
• W2059791166 hasConceptScore W2059791166C55493867 @default.
• W2059791166 hasConceptScore W2059791166C61276311 @default.
• W2059791166 hasConceptScore W2059791166C71240020 @default.
• W2059791166 hasConceptScore W2059791166C8010536 @default.
• W2059791166 hasIssue "5" @default.
• W2059791166 hasLocation W20597911661 @default.
• W2059791166 hasLocation W20597911662 @default.

• next