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- W2059791396 abstract "Mixed oxide electrodes with nominal composition Ti/[Ru(0.3)Ti(0.6)Ce(0.1−x)]O2[Nb2O5](x), (0≤x≤0.1) were prepared through a process of thermal decomposition (450 °C) of chloride precursor mixture solutions. Composition effects on the surface properties were investigated and the oxide electrodes were characterized in acid solution: ex situ by XRD and in situ by open circuit potential measurements (Eoc), cyclic voltammetry (CV), the double-layer capacitance (CV and electrochemical impedance spectroscopy techniques) and roughness factor (CV). Except the Eoc, all parameters varied with the electrode composition. It was shown that the presence of CeO2 increases the electrochemical active area, but it makes the coating less stable when submitted to continuous potential cycles because of cathodic dissolution of this oxide. By adding Nb2O5 this instability can be lowered. The maximum activity (voltammetric charge) was observed with the [Ru(0.3)Ti(0.6)Ce(0.07)]O2[Nb2O5](0.03) composition." @default.
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- W2059791396 date "2003-06-01" @default.
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- W2059791396 title "Investigation of surface properties of Ru-based oxide electrodes containing Ti, Ce and Nb" @default.
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- W2059791396 doi "https://doi.org/10.1016/s0013-4686(03)00262-7" @default.
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