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- W2059804578 abstract "ZnO/ZnSxSe1−x core–shell nanowire arrays on a silicon substrate were successfully prepared via a hydrothermal method followed by chemical vapor deposition (CVD) of the ZnSxSe1−x shell. By optimizing the CVD growth conditions, a crystalline ZnSxSe1−x shell and well-aligned ZnO/ZnSxSe1−x interface were achieved, which plays an important role towards the enhanced performance of photocatalytic activity. The introduction of the crystalline, lattice-matched ZnSxSe1−x shell to ZnO nanowires significantly enhances the photocatalytic and photoelectrocatalytic activity under UV light irradiation. More attractively, after being combined with the ZnSxSe1−x shell, the visible light photoelectrocatalytic activity of the ZnO/ZnSxSe1−x core–shell nanowires is observed. The performance enhancement of ZnO/ZnSxSe1−x core–shell nanowires under irradiation is mainly due to matching lattice and band energy level alignment between the crystalline ZnSxSe1−x shell and ZnO nanowire core. The high crystal quality of the ZnSxSe1−x shell and the band alignment of the ZnO/ZnSxSe1−x core–shell greatly enhance the charge separation efficiency and prolong the life-time of photogenerated charge carriers. Our finding is expected to provide a new insight into the fabrication of novel and high performance nanowire based core–shell photocatalysts." @default.
- W2059804578 created "2016-06-24" @default.
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- W2059804578 date "2014-09-05" @default.
- W2059804578 modified "2023-10-14" @default.
- W2059804578 title "Crystalline ZnO/ZnS<sub>x</sub>Se<sub>1−x</sub>core–shell nanowire arrays for efficient visible-light photoelectrocatalysis" @default.
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- W2059804578 doi "https://doi.org/10.1039/c4ta04293j" @default.
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