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• W2059830082 startingPage "747" @default.
• W2059830082 abstract "Thermoelectric power studies of polyacetylene have been carried out as a function of dopant concentration and temperature. The thermopower of pure trans-(CH)x is large (S = +850 μ V°K) and positive consistent with p-type material. With iodine doping, (CHIy)x, the thermopower remains positive over the full range of concentration 0 < y < 0.22. The semiconductor-metal transition is clearly observed at nc ≅ 3 mole %; S falls dramatically from S = +850 μ V°K at y = 0.003 to S = +30 μ V°K at y = 0.03. At higher concentrations, S remains nearly constant saturating at +18 μ V°K in the heavily doped metallic polymer. Temperature dependences are consistent with metallic behavior at the highest dopant concentrations and hopping transport in the undoped and lightly doped polymer." @default.
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• W2059830082 date "1979-03-01" @default.
• W2059830082 modified "2023-10-16" @default.
• W2059830082 title "Semiconductor-metal transition in doped (CH)x: Thermoelectric power" @default.
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• W2059830082 doi "https://doi.org/10.1016/0038-1098(79)90153-4" @default.
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