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- W2059849265 abstract "Abstract The polymerization of cyclohexene oxide (CHO) by various organoaluminum compounds such as R3Al (R = Me, Et, i-Bu), Et2AlCl, and EtAlCl2 is reported. Ethyl-substituted aluminum compounds were found to be very effective for this polymerization. As more chlorine atom is substituted on the aluminum atom, the polymer yield was increased though the molecular weight was decreased. The polymer yields at varying monomer-to-catalyst mole ratios (M/C) were similar (80–93%). The temperature and solvent effect for the present polymerization were also studied. The present poly(CHO) was a less stereoregular (atactic) isomer, regardless of catalysts and polymerization conditions. The resulting poly(CHO) was a white powder ad was soluble in aromatic and halogenated hydrocarbon solvents such as benzene, chlorobenzene, CCl4, chloroform, etc." @default.
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- W2059849265 date "1993-08-01" @default.
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- W2059849265 title "Polymerization of Cyclohexene Oxide By Organoaluminum Compounds" @default.
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- W2059849265 doi "https://doi.org/10.1080/10601329308009428" @default.
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