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• W2059883911 startingPage "4287" @default.
• W2059883911 abstract "Mass spectrometric methods are used for an investigation of the C–O bond formation between alkynes and alcohols mediated by cationic gold(I) complexes. In the condensed-phase catalysis, an efficient coupling to the corresponding enol ethers has been observed. In the gas phase, however, kinetic and entropic restrictions are too large for both bare Au+ as well as (CH3)3PAu+ to permit bond formation in strictly bimolecular collisions occurring at thermal energies. The experimental findings are complemented by a theoretical study of the Au+/C2H2/CH3OH system using density functional theory." @default.
• W2059883911 created "2016-06-24" @default.
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• W2059883911 date "2005-11-01" @default.
• W2059883911 modified "2023-10-16" @default.
• W2059883911 title "A gas-phase study of the gold-catalyzed coupling of alkynes and alcohols" @default.
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• W2059883911 doi "https://doi.org/10.1016/j.ica.2005.03.023" @default.
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