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- W2059891909 abstract "The complexes cis-PtCl(C2H5)(diphosphine) (diphosphine = 1,3-bis(diphenylphosphino)propane and 1,4-bis(diphenylphosphino)butane) have been used as model compounds for the hydroformylation of olefin catalyzed by the system PtCl2/diphosphine/SnCl2. They react with SnCl2 to yield the corresponding trichlorostannate complexes cis-Pt(SnCl3)(C2H5)(diphosphine), which in the absence of free ethylene decompose to form the dichloro species cis-PtCl2(diphosphine) via an unstable hydrido species. Both the chloro- and trichlorostannate-alkyl complexes react with CO to give the acyl species cis-PtX(COC2H5)(diphosphine) (X = Cl or SnCl3). When the diphosphine is 1,4-bis(diphenylphosphino)butane, oligomeric acyl complexes of trans geometry are formed. Preliminary studies of the reactivity of the acyl complexes with molecular hydrogen show that only the complexes bearing the Pt—SnCl3 moiety react at ambient conditions giving propanal as the only observed organic product." @default.
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- W2059891909 date "1988-04-01" @default.
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- W2059891909 title "On the mechanism of platinum(II)/SnCl2 catalyzed hydroformylation of olefins. Studies of the reactivity of alkyl complexes containing chelating diphosphines" @default.
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- W2059891909 doi "https://doi.org/10.1016/0022-328x(88)80485-6" @default.
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