Matches in SemOpenAlex for { <https://semopenalex.org/work/W2059894776> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2059894776 endingPage "39" @default.
- W2059894776 startingPage "29" @default.
- W2059894776 abstract "Reversible charge transfer on boron doped diamond (BDD) electrodes was studied using cyclic voltammetry and electrochemical impedance spectroscopy. Polycrystalline diamond films of 5 μm thickness with 200 and 3000 ppm boron content were prepared by chemical vapour deposition on niobium substrate. The samples were mounted in a Teflon holder and used as rotating disk electrodes (RDE) with rotation frequencies between 0 and 4000 rpm. The electrochemical measurements were carried out in aqueous electrolyte solutions of 0.5 M Na2SO4 + 5 mM K3[Fe(CN)6]/K4[Fe(CN)6] and 0.1 M KCl + 5 mM [Ru(NH3)6]Cl2/[Ru(NH3)6]Cl3. The electrochemical redox behaviour of the BDD electrodes was found to differ significantly from that of an active Pt electrode. The deviations are indicated by a large peak potential difference and a shift of the peak potentials in cyclic voltammograms with increasing sweep rate. At rotating electrodes lower limiting current densities are found and the impedance diagrams exhibit an additional capacitive impedance element at high frequencies. The results are described quantitatively by an impedance model which is based on partial blocking of the diamond surface." @default.
- W2059894776 created "2016-06-24" @default.
- W2059894776 creator A5025481368 @default.
- W2059894776 creator A5041699777 @default.
- W2059894776 date "2003-12-01" @default.
- W2059894776 modified "2023-09-27" @default.
- W2059894776 title "The impedance of fast charge transfer reactions on boron doped diamond electrodes" @default.
- W2059894776 cites W1489345683 @default.
- W2059894776 cites W1559801491 @default.
- W2059894776 cites W1964521111 @default.
- W2059894776 cites W2002495067 @default.
- W2059894776 cites W2025625917 @default.
- W2059894776 cites W2031752217 @default.
- W2059894776 cites W2036380342 @default.
- W2059894776 cites W2040264368 @default.
- W2059894776 cites W2055923719 @default.
- W2059894776 cites W2059390006 @default.
- W2059894776 cites W2064739071 @default.
- W2059894776 cites W2073424019 @default.
- W2059894776 cites W2073675089 @default.
- W2059894776 cites W2077874373 @default.
- W2059894776 cites W2082529460 @default.
- W2059894776 cites W2092686954 @default.
- W2059894776 cites W2098084363 @default.
- W2059894776 cites W2118336613 @default.
- W2059894776 cites W2909736671 @default.
- W2059894776 cites W2953275904 @default.
- W2059894776 cites W4239920293 @default.
- W2059894776 doi "https://doi.org/10.1016/j.electacta.2003.04.003" @default.
- W2059894776 hasPublicationYear "2003" @default.
- W2059894776 type Work @default.
- W2059894776 sameAs 2059894776 @default.
- W2059894776 citedByCount "45" @default.
- W2059894776 countsByYear W20598947762012 @default.
- W2059894776 countsByYear W20598947762013 @default.
- W2059894776 countsByYear W20598947762016 @default.
- W2059894776 countsByYear W20598947762017 @default.
- W2059894776 countsByYear W20598947762018 @default.
- W2059894776 countsByYear W20598947762019 @default.
- W2059894776 countsByYear W20598947762021 @default.
- W2059894776 countsByYear W20598947762022 @default.
- W2059894776 crossrefType "journal-article" @default.
- W2059894776 hasAuthorship W2059894776A5025481368 @default.
- W2059894776 hasAuthorship W2059894776A5041699777 @default.
- W2059894776 hasConcept C113196181 @default.
- W2059894776 hasConcept C147789679 @default.
- W2059894776 hasConcept C159985019 @default.
- W2059894776 hasConcept C171250308 @default.
- W2059894776 hasConcept C17525397 @default.
- W2059894776 hasConcept C185592680 @default.
- W2059894776 hasConcept C192562407 @default.
- W2059894776 hasConcept C2776921476 @default.
- W2059894776 hasConcept C2777869211 @default.
- W2059894776 hasConcept C2781060269 @default.
- W2059894776 hasConcept C43617362 @default.
- W2059894776 hasConcept C52859227 @default.
- W2059894776 hasConcept C57410435 @default.
- W2059894776 hasConcept C68801617 @default.
- W2059894776 hasConcept C7040849 @default.
- W2059894776 hasConceptScore W2059894776C113196181 @default.
- W2059894776 hasConceptScore W2059894776C147789679 @default.
- W2059894776 hasConceptScore W2059894776C159985019 @default.
- W2059894776 hasConceptScore W2059894776C171250308 @default.
- W2059894776 hasConceptScore W2059894776C17525397 @default.
- W2059894776 hasConceptScore W2059894776C185592680 @default.
- W2059894776 hasConceptScore W2059894776C192562407 @default.
- W2059894776 hasConceptScore W2059894776C2776921476 @default.
- W2059894776 hasConceptScore W2059894776C2777869211 @default.
- W2059894776 hasConceptScore W2059894776C2781060269 @default.
- W2059894776 hasConceptScore W2059894776C43617362 @default.
- W2059894776 hasConceptScore W2059894776C52859227 @default.
- W2059894776 hasConceptScore W2059894776C57410435 @default.
- W2059894776 hasConceptScore W2059894776C68801617 @default.
- W2059894776 hasConceptScore W2059894776C7040849 @default.
- W2059894776 hasIssue "1" @default.
- W2059894776 hasLocation W20598947761 @default.
- W2059894776 hasOpenAccess W2059894776 @default.
- W2059894776 hasPrimaryLocation W20598947761 @default.
- W2059894776 hasRelatedWork W1969933858 @default.
- W2059894776 hasRelatedWork W1981154045 @default.
- W2059894776 hasRelatedWork W2044740642 @default.
- W2059894776 hasRelatedWork W2062013085 @default.
- W2059894776 hasRelatedWork W2095518037 @default.
- W2059894776 hasRelatedWork W2157120141 @default.
- W2059894776 hasRelatedWork W2159779271 @default.
- W2059894776 hasRelatedWork W2359037705 @default.
- W2059894776 hasRelatedWork W2360816897 @default.
- W2059894776 hasRelatedWork W2618613228 @default.
- W2059894776 hasVolume "49" @default.
- W2059894776 isParatext "false" @default.
- W2059894776 isRetracted "false" @default.
- W2059894776 magId "2059894776" @default.
- W2059894776 workType "article" @default.